Climate-driven changes in sedimentation rate influence phosphorus burial along continental margins of the northwestern Mediterranean

Abstract

[EN]The burial of phosphorus (P) in continental margin sediments is a critical component of the marine reactive P budget, and thus an important factor in marine biological productivity. We determined downcore records of P from a site drilled on the upper slope of the Gulf of Lions (PRGL 1), northwestern Mediterranean Sea. Changes in total P content were monitored from Marine Isotope Stage (MIS) 6 to MIS 11. In addition, in two selected intervals (248–277 ka and 306–342 ka) the total P record was expanded by adding detailed geochemical analyses of the various P fractions, including oxyhydroxide-associated P, authigenic P, detrital P and organic P. Increased sedimentation rates during glacials owing to seaward migration of the Rhone's mouth, enhanced the burial of reactive P (oxyhydroxide-associated + authigenic + organic) phases by decreasing its time at the reactive sediment/water interface, in turn resulting in increasing proportion of authigenic to detrital phosphorus. The inverse was found for interglacial stages.