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Título
Zr-MOF-808 as Catalyst for Amide Esterification
Autor(es)
Materia
Zr-MOF
Catalyst
Amide esterification
Clasificación UNESCO
2210.01-1 Estructura y Reactividad de Catalizadores Sólidos
2306 Química Orgánica
Fecha de publicación
2021
Editor
Wiley
Citación
Zr-MOF-808 as Catalyst for Amide Esterification Chem. Eur. J. 2021, 27, 4588 –
Resumen
[EN]In this work, zirconium-based metal–organic framework Zr-MOF-808-P has been found to be an efficient and versatile catalyst for amide esterification. Comparing with previously reported homogeneous and heterogeneous catalysts, Zr-MOF-808-P can promote the reaction for a wide range of primary, secondary and tertiary amides with n-butanol as nucleophilic agent. Different alcohols have been employed in amide esterification with quantitative yields. Moreover, the catalyst acts as a heterogeneous catalyst and could be reused for at least five consecutive cycles. The amide esterification mechanism has been studied on the Zr-MOF-808 at molecular level by in situ FTIR spectroscopic technique and kinetic study.
URI
DOI
10.1002/chem.202003752
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