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dc.contributor.authorAlexandre-Franco, María
dc.contributor.authorFernández-González, Carmen
dc.contributor.authorGómez-Serrano, Vicente
dc.contributor.authorBogeat Barroso, Adrián 
dc.date.accessioned2023-10-05T12:44:26Z
dc.date.available2023-10-05T12:44:26Z
dc.date.issued2015
dc.identifier.citationBarroso-Bogeat, A., Alexandre-Franco, M., Fernández-González, C., Gómez-Serrano, V. (2015). Preparation of activated carbon-metal (hydr) oxide materials by thermal methods. Thermogravimetric-mass spectrometric (TG-MS) analysis, Journal of Analytical and Applied Pyrolysis, 116 pp 243-252. http://dx.doi.org/10.1016/j.jaap.2015.09.004es_ES
dc.identifier.issn0165-2370
dc.identifier.urihttp://hdl.handle.net/10366/153183
dc.description.abstract[EN] tActivated carbon (AC)-metal (hydr) oxide (MO) materials prepared by wet impregnation of a commercialAC with Al3+, Fe3+, Zn2+, SnCl2, TiO2and WO42−in water at pH between 1.37 and 9.54 in two successivesoaking and oven-drying steps are analysed by thermogravimetry-mass spectrometry (TG-MS) between25 and 900◦C. Under identical conditions, a blank sample (ACB) was first prepared using deionized waterand then thermally analyzed. The mass loss in the TG analysis is 1.35 wt% for AC, 2.12 wt% for ACB, andbetween 2.47 and 23.20 wt% for the AC-MO materials. For these materials, it depends on the impregnationagent and varies by SnCl2> Fe3+> Al3+> Zn2+> WO42−> TiO2. The number of thermal effects giving off CO2and CO is larger with the Al3+, Fe3+and Zn2+ions than with SnCl2, TiO2and WO42−. It is so in particular forCO2with the Fe3+ion and for CO with the Al3+ion. In general, the release of CO at high temperature hasbeen associated with the carbothermal reduction of metal oxides. As a result of the reaction low-meltingpoint metals such as Al, Zn and Sn, unlike Fe and W, are formed which vaporize and thereby contribute tothe mass loss. Only with Fe3+and TiO2, the amount of desorbed water is larger by dehydroxylation thanby dehydration. The masses of evolved H2O, CO2and CO are by far higher with SnCl2, whereas they arelower with TiO2and WO42−.es_ES
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectActivated carbones_ES
dc.subjectMetal ions/metal oxideses_ES
dc.subjectActivated carbon-metal (hydr)oxide materialses_ES
dc.subjectThermal behaviores_ES
dc.subjectTG-MS analysises_ES
dc.titlePreparation of activated carbon-metal (hydr) oxide materials by thermal methods. Thermogravimetric-mass spectrometric (TG-MS) analysises_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publishversionhttp://dx.doi.org/10.1016/j.jaap.2015.09.004es_ES
dc.subject.unesco2303 Química Inorgánicaes_ES
dc.subject.unesco3321.02 Productos Químicos derivados del Carbónes_ES
dc.identifier.doi10.1016/j.jaap.2015.09.004
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.journal.titleJournal of Analytical and Applied Pyrolysises_ES
dc.volume.number116es_ES
dc.page.initial243es_ES
dc.page.final252es_ES
dc.type.hasVersioninfo:eu-repo/semantics/acceptedVersiones_ES


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