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Titanocene-Promoted Intermolecular Couplings of Epoxides with Nitriles. An Easy Access to β-Hydroxyketones
dc.contributor.authorFernández Mateos, Alfonso
dc.contributor.authorEncinas Madrazo, Soledad
dc.contributor.authorHerrero Teijón, Pablo 
dc.contributor.authorRubio González, María Rosa 
dc.date.accessioned2024-01-12T12:21:48Z
dc.date.available2024-01-12T12:21:48Z
dc.date.issued2009
dc.identifier.citationFernández Mateos, A., Herrero Teijón, P., Encinas Madrazo, S. & Rubio González, R. (2009). Titanocene-Promoted Intermolecular Couplings of Epoxides with Nitriles. An Easy Access to β-Hydroxyketones. The Journal of Organic Chemistry, 74(10), 3913–3918. https://doi.org/10.1021/jo900479ves_ES
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/10366/154179
dc.description.abstract[EN]Radical couplings of epoxides and nitriles mediated by Cp2TiCl provide a diastereoselective route to the synthesis of β-hydroxyketones. The conditions of this “aldol-like” reaction are mild enough to avoid the dehydration of the β-hydroxyketone. The scope of the coupling reaction with functionalized and tetrasubstituted epoxides has been studied. The radical character of the coupling reactions is demonstrated.es_ES
dc.format.mimetypeapplication/pdf
dc.language.isoenges_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectQuímica orgánicaes_ES
dc.subjectNitriloses_ES
dc.subjectRadicales (Química)es_ES
dc.subjectCloruroses_ES
dc.subjectReacciones químicases_ES
dc.titleTitanocene-Promoted Intermolecular Couplings of Epoxides with Nitriles. An Easy Access to β-Hydroxyketoneses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publishversionhttps://doi.org/10.1021/jo900479ves_ES
dc.subject.unesco2306 Química Orgánicaes_ES
dc.identifier.doi10.1021/jo900479v
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.essn1520-6904
dc.journal.titleThe Journal of Organic Chemistryes_ES
dc.volume.number74es_ES
dc.issue.number10es_ES
dc.page.initial3913es_ES
dc.page.final3918es_ES
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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