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Titanocene‐Promoted Eliminations on Epoxy Alcohols and Epoxy Esters
dc.contributor.authorFernández Mateos, Alfonso
dc.contributor.authorEncinas Madrazo, Soledad
dc.contributor.authorHerrero Teijón, Pablo 
dc.contributor.authorRubio González, María Rosa 
dc.date.accessioned2024-01-12T12:29:12Z
dc.date.available2024-01-12T12:29:12Z
dc.date.issued2010
dc.identifier.citationFernández Mateos, A., Herrero Teijón, P., Encinas Madrazo, S. & Rubio González, R. (2010). Titanocene‐Promoted Eliminations on Epoxy Alcohols and Epoxy Esters. European Journal of Organic Chemistry, 2010(5), 856–861. https://doi.org/10.1002/ejoc.200901222es_ES
dc.identifier.issn1434-193X
dc.identifier.urihttp://hdl.handle.net/10366/154182
dc.description.abstract[EN]The reaction of a series of 2,3-epoxy alcohols and the corresponding formates, acetates, and benzoates promoted by Cp2TiCl has been studied. The different outcome of the reaction of epoxy derivatives has been rationalized in terms of mechanistically biased processes. After homolytic oxirane cleavage, four main types of reaction were found: dehydroxylation, decarboxylation, dehydrogenation, and deoxygenation. The reaction products varied according to the substitution pattern. The radical nature of these eliminations is demonstrated.es_ES
dc.format.mimetypeapplication/pdf
dc.language.isoenges_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectRadical reactionses_ES
dc.subjectTitaniumes_ES
dc.subjectEliminationes_ES
dc.subjectEpoxideses_ES
dc.subjectAlcoholses_ES
dc.subjectOxygen heterocycleses_ES
dc.titleTitanocene‐Promoted Eliminations on Epoxy Alcohols and Epoxy Esterses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publishversionhttps://doi.org/10.1002/ejoc.200901222es_ES
dc.subject.unesco2306 Química Orgánicaes_ES
dc.identifier.doi10.1002/ejoc.200901222
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.identifier.essn1099-0690
dc.journal.titleEuropean Journal of Organic Chemistryes_ES
dc.volume.number2010es_ES
dc.issue.number5es_ES
dc.page.initial856es_ES
dc.page.final861es_ES
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersiones_ES


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