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Synthesis of diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6-dicarboxylate by Pd-catalyzed intramolecular allylic alkylation. Stereoselective preparation of its optically homogeneous form from R-(−)-carvone
dc.contributor.authorGalán Fernández, Raquel
dc.contributor.authorClemente Tejeda, David
dc.contributor.authorRío Nieto, Enrique del 
dc.contributor.authorBermejo, Francisco A.
dc.date.accessioned2026-02-27T08:41:54Z
dc.date.available2026-02-27T08:41:54Z
dc.date.issued2010
dc.identifier.citationGalán-Fernández, R., Clemente-Tejeda, D., Río-Nieto, E. del, & Bermejo, F. A. (2010). Synthesis of diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6-dicarboxylate by Pd-catalyzed intramolecular allylic alkylation. Stereoselective preparation of its optically homogeneous form from R-(−)-carvone. Tetrahedron, 66(42), 8247–8253. https://doi.org/10.1016/j.tet.2010.08.051es_ES
dc.identifier.issn0040-4020
dc.identifier.urihttp://hdl.handle.net/10366/170166
dc.description.abstract[EN]A new route to racemic diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6- dicarboxylate (±)-1a by means of a palladium-catalyzed intramolecular allylic alkylation exercised on malonate-ester derivatives has been developed from R-(-)-carvone. The stereocontrolled synthesis of the enantiomerically pure (-)-1b by application of a six-step reactions sequence with a 28% overall yield from acetal 8, has been accomplished.es_ES
dc.format.mimetypeapplication/pdf
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAllylic alkylationes_ES
dc.subjectMonoterpeneses_ES
dc.subjectPd catalysises_ES
dc.subjectStereoselective synthesises_ES
dc.titleSynthesis of diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6-dicarboxylate by Pd-catalyzed intramolecular allylic alkylation. Stereoselective preparation of its optically homogeneous form from R-(−)-carvonees_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publishversionhttps://doi.org/10.1016/j.tet.2010.08.051es_ES
dc.identifier.doi10.1016/j.tet.2010.08.051
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses_ES
dc.journal.titleTetrahedrones_ES
dc.volume.number66es_ES
dc.issue.number42es_ES
dc.page.initial8247es_ES
dc.page.final8253es_ES
dc.type.hasVersioninfo:eu-repo/semantics/draftes_ES


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