Título
Multipole-induced dipole contributions to the far-infrared spectra of diatomic molecules in non-polar solvents
Autor(es)
Palabras clave
Análisis espectral
Moléculas
Spectrum analysis
Molecules
Fecha de publicación
2009-10-07
Citación
Medina, A., Roco, J.M.M., Hernández, A.C., Velasco, S. (2004). Multipole — Induced Dipole Contributions to the Far-Infrared Spectra of Diatomic Molecules in Non-Polar Solvents. In: Samios, J., Durov, V.A. (eds) Novel Approaches to the Structure and Dynamics of Liquids: Experiments, Theories and Simulations. NATO Science Series, vol 133. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-2384-2_20
Resumen
[EN]In this paper we overview our work on far-infrared spectroscopy of both hetero- and homonuclear diatomic molecules in nonpolar fluids. Special attention is paid to electric multipolar induced contributions. From comparison between theoretical and experimental spectra estimation of the leading multipoles of CO and N2 molecules has been obtained. Also a temperature and density dependence analysis of many-body cancellation effects in the different pure induced components of the far-infrared integrated absorption coeffcient of CO in liquid Ar is reported.
Descripción
Trabajo sobre la espectroscopía infrarroja de moléculas diatómicas homo y hetero-nuclear en fluidos no polares
URI
DOI
10.1007/978-1-4020-2384-2_20
Versión del editor
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