<?xml version="1.0" encoding="UTF-8"?><?xml-stylesheet type="text/xsl" href="static/style.xsl"?><OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd"><responseDate>2026-09-16T22:43:55Z</responseDate><request verb="GetRecord" identifier="oai:gredos.usal.es:10366/149577" metadataPrefix="uketd_dc">https://gredos.usal.es/oai/request</request><GetRecord><record><header><identifier>oai:gredos.usal.es:10366/149577</identifier><datestamp>2022-05-12T03:00:32Z</datestamp><setSpec>com_10366_4128</setSpec><setSpec>com_10366_4055</setSpec><setSpec>com_10366_3946</setSpec><setSpec>com_10366_3823</setSpec><setSpec>com_10366_4756</setSpec><setSpec>com_10366_4746</setSpec><setSpec>com_10366_143092</setSpec><setSpec>com_10366_143090</setSpec><setSpec>com_10366_123103</setSpec><setSpec>col_10366_4136</setSpec><setSpec>col_10366_68519</setSpec><setSpec>col_10366_143096</setSpec></header><metadata><uketd_dc:uketddc xmlns:uketd_dc="http://naca.central.cranfield.ac.uk/ethos-oai/2.0/" xmlns:doc="http://www.lyncode.com/xoai" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xmlns:uketdterms="http://naca.central.cranfield.ac.uk/ethos-oai/terms/" xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xsi:schemaLocation="http://naca.central.cranfield.ac.uk/ethos-oai/2.0/ http://naca.central.cranfield.ac.uk/ethos-oai/2.0/uketd_dc.xsd">
<dc:title>The late Miocene – early Pliocene offshore onshore sedimentary records in the vicinity of Gibraltar</dc:title>
<dc:creator>Bulian, Francesca</dc:creator>
<uketdterms:advisor>Sierro Sánchez, Francisco Javier</uketdterms:advisor>
<dcterms:abstract>[EN] Atlantic gateways, progressively isolating the Mediterranean Basin from the Global&#xd;
Ocean. This change in gateway configuration modified radically the circulation patterns,&#xd;
water residence time and salinity of the Mediterranean waters leading to the&#xd;
extraordinary paleoenvironmental change known as the Messinian Salinity Crisis&#xd;
(MSC). This event lasted between 5.97 and 5.33 Ma and led to the deposition of huge&#xd;
evaporite accumulations both in the marginal and deep Mediterranean basins. Now,&#xd;
more than 50 years after the Glomar challenger ventured Mediterranean waters, and the&#xd;
evaporites in deep basins were discovered, the debate regarding the conditions and&#xd;
timing of the deposition of the Mediterranean salt giant is still ongoing as many theories&#xd;
regarding the dynamics and chronology of the Gibraltar arc gateway/s closure and&#xd;
reopening are waiting to be validated.&#xd;
In this optic, the study of cores and outcrops in the proximity of the current Strait&#xd;
of Gibraltar is essential to better understand the evolution of the Mediterranean –&#xd;
Atlantic gateways. In this thesis we perform a detailed planktic and benthic foraminifer,&#xd;
geochemical (XRF and stable isotopes) and sedimentological analyses of Alboran Basin&#xd;
ODP Site 976, DSDP Site 121, industrial boreholes Andalucia-G1, Alboran-A1, landbased sections from southern Spanish basins including Nijar, Sorbas and Malaga and&#xd;
Montemayor-1 core from the Guadalquivir Basin. The obtained results, paired with the&#xd;
interpretation of seismic profiles acquired in the Alboran Basin gave some new insights&#xd;
and results towards the better understanding of the Late Miocene to early Pliocene&#xd;
evolution of the Mediterranean – Atlantic gateways and the effects of the restriction on&#xd;
the Mediterranean environments before and after the MSC. The main outcomes of this&#xd;
thesis are outlined in the next paragraphs, as follows:&#xd;
→ A high-resolution planktonic foraminifer stratigraphy performed on Sites 976&#xd;
and Montemayor-1 in combination with the analyses of the astronomically&#xd;
driven cyclical changes in the geochemical record enabled the astronomical&#xd;
tuning of the two locations. Having a firm age model allowed to pinpoint the&#xd;
moment when the uplift of the Gibraltar arc gateway/s started affecting the&#xd;
Mediterranean Basin and Betic corridor.&#xd;
→ The first sign of the Mediterranean – Atlantic gateway restriction is visible in the&#xd;
Mediterranean basin from 7.17 Ma, when active tectonism at the Gibraltar arc&#xd;
started uplifting the Betic and Rifian corridors. At ODP Site 976, the uplift is&#xd;
visible from the increase in terrigenous input arriving to the Alboran basin and&#xd;
parallel higher sedimentation rates related with an increased river erosion. On&#xd;
the other hand, the shift from benthic foraminifer open-marine high oxygen&#xd;
fauna to shallow infaunal taxa, tolerant to a wide range of conditions and&#xd;
suboptimal oxygen levels, paired with a significant drop in benthic δ13C values&#xd;
suggests that the gateway restriction led to the decrease in bottom water oxygen&#xd;
levels and increase in its residence time much earlier than the onset of the MSC.&#xd;
→ A correlation between data from ODP Site 976 and other Mediterranean records&#xd;
confirmed that the 7.17 Ma gateway restriction, affected at the same time different locations all over the Mediterranean, inferring a Mediterranean-scale&#xd;
change in thermohaline circulation. From these data we concluded that the West&#xd;
Alboran Basin (WAB) and the East Alboran Basin (EAB) were not separated by&#xd;
a sill at that time but were both part of the Mediterranean realm. Furthermore,&#xd;
it was possible to create a refined Mediterranean circulation model for before&#xd;
and after the 7.17 Ma event.&#xd;
→ The gateway restriction registered in the Mediterranean record since 7.17 Ma, is&#xd;
visible also from the geochemical data of Montemayor-1 core in the&#xd;
Guadalquivir Basin. Because the geochemical data from Montemyor-1 reveals&#xd;
that after 7.15-7.17 Ma, the Guadalquivir Basin was bathed by only one water&#xd;
mass, probably Atlantic, we believe that the connection between the&#xd;
Mediterranean and Atlantic through the Betic corridor was restricted at that&#xd;
time. Consequently, we suggest that the restriction of the last Betic gateway, the&#xd;
Guadalhorce Basin, could have happened at 7.15-7.17 Ma and caused the abovementioned changes in the Mediterranean paleoenvironment.&#xd;
→ Because the gateway restriction was contemporaneous with the global Late&#xd;
Miocene Carbon Isotope Shift (LMCIS) it was important to discern between&#xd;
global and local effects and compare the Mediterranean and global records.&#xd;
Given the synchronism of the global and local Mediterranean change in the δ13C&#xd;
record, a global effect certainly affected the Mediterranean Basin. However,&#xd;
opposite phase relations of the global and local δ13C signals with orbital&#xd;
parameters, paired with a higher magnitude change identified in our WAB&#xd;
isotope record suggests that the local imprint overruled the global one. A similar&#xd;
effect can be seen in the Montemayor-1 record, where apart from the changes&#xd;
related to the uplift of the Gibraltar arc, a global signal cannot be overruled.&#xd;
→ Finally, through the development of this thesis it is shown how the dark layer&#xd;
often enriched in organic matter, present at the Miocene – Pliocene boundary in&#xd;
several Mediterranean marginal and deep basins, suggests that the Zanclean&#xd;
reflooding created water column stratification, and reduced bottom water&#xd;
oxygen levels. Such stratification could be the result of a sinking of more saline&#xd;
Atlantic water mass entering into a less saline Mediterranean Basin still under&#xd;
the influence of the Paratethys. The benthic foraminifer repopulation sequence&#xd;
identified at the base of the Pliocene shows similarities with more recent events&#xd;
of repopulation of hostile environments or following low-oxic episodes during&#xd;
sapropel deposition. However, Atlantic values of the benthic δ13C registered in&#xd;
the Alboran Basin suggest that bottom water renewal and circulation were&#xd;
efficient during the early Zanclean, preventing the reduction of δ13C at the&#xd;
seafloor seen after 7.17 Ma. Furthermore, the slight discrepancies in the benthic&#xd;
foraminifer repopulation sequences of the marginal basins at the Miocene –&#xd;
Pliocene boundary, and the much lighter benthic δ13C values in the Malaga&#xd;
Basin can suggest a diachronous reflooding of the shallower marginal basins.</dcterms:abstract>
<dcterms:issued>2022</dcterms:issued>
<dc:type>info:eu-repo/semantics/doctoralThesis</dc:type>
<dc:language xsi:type="dcterms:ISO639-2">spa</dc:language>
<dcterms:isReferencedBy>http://hdl.handle.net/10366/149577</dcterms:isReferencedBy>
<dcterms:hasFormat>https://gredos.usal.es/bitstream/10366/149577/4/BulianF.pdf.txt</dcterms:hasFormat>
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<dcterms:license>https://gredos.usal.es/bitstream/10366/149577/3/license.txt</dcterms:license>
<uketdterms:checksum xsi:type="uketdterms:MD5">c01660a91797318ab11c17561332e8ad</uketdterms:checksum>
<dc:identifier xsi:type="dcterms:URI">https://gredos.usal.es/bitstream/10366/149577/1/BulianF.pdf</dc:identifier>
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<dc:rights>Attribution-NonCommercial-NoDerivatives 4.0 Internacional</dc:rights>
<dc:subject>Tesis y disertaciones académicas</dc:subject>
<dc:subject>Universidad de Salamanca (España)</dc:subject>
<dc:subject>Tesis Doctoral</dc:subject>
<dc:subject>Academic dissertations</dc:subject>
<dc:subject>Registros sedimentarios</dc:subject>
<dc:subject>Mioceno tardío</dc:subject>
<dc:subject>Plioceno temprano</dc:subject>
<dc:subject>Sondeo marino</dc:subject>
<dc:subject>Gibraltar</dc:subject>
<dc:identifier>10.14201/gredos.149577</dc:identifier>
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