2026-09-14T14:16:42Zhttps://gredos.usal.es/oai/request

oai:gredos.usal.es:10366/1541472025-04-30T19:51:19Zcom_10366_4155com_10366_4055com_10366_3946com_10366_3823col_10366_4156

Rabanedo Clemente, R. Fernández Mateos, Alfonso Herrero Teijón, Pablo Rubio González, María Rosa 2006 [EN]The reductive radical cyclizations of several epoxy esters have been achieved using titanocene chloride. The tether length from the initial radical to the carbonyl acceptor is the key of the reactions. We obtained products from radical cyclization onto carbonyl formate and products from formate and hydrogen elimination. The stereochemical outcome of the 5-exo radical cyclization of two diastereomers is reported. A radical cascade cyclization of an unsaturated epoxy formate is also described. application/pdf http://hdl.handle.net/10366/154147 eng Elsevier 2306 Química Orgánica Radical reactions of epoxy esters induced by titanocene chloride info:eu-repo/semantics/article TEXT Gredos. Repositorio Documental de la Universidad de Salamanca Hispana