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oai:gredos.usal.es:10366/1541812026-01-15T10:53:18Zcom_10366_4155com_10366_4055com_10366_3946com_10366_3823col_10366_4156

Simmonds, M.S.J. Fernández Mateos, Alfonso Herrero Teijón, Pablo Pascual Coca, Gustavo Rubio González, María Rosa 2024-01-12T12:25:29Z 2024-01-12T12:25:29Z 2010 Fernández Mateos, A., Herrero Teijón, P., Pascual Coca, G., Simmonds, M.S.J. & Rubio González, R. (2010). Synthesis of limonoid CDE fragments related to limonin and nimbinim. Tetrahedron, 66(36), 7257–7261. https://doi.org/10.1016/j.tet.2010.07.020 0040-4020 http://hdl.handle.net/10366/154181 10.1016/j.tet.2010.07.020 [EN]A practical, brief and selective synthesis of limonoid CDE fragments from a readily available starting diketone is described. The key step is a cationic electrocyclization promoted by strong acids. In general the methodology has been demonstrated for compounds with sensitive furane and thiophene substituents to obtain diverse substituted indenones. Several of the compounds obtained show significant antifeedant activity against Spodoptera littoralis. eng http://creativecommons.org/licenses/by-nc-nd/4.0/ info:eu-repo/semantics/openAccess Attribution-NonCommercial-NoDerivatives 4.0 Internacional Limonoids Nazarov cyclization Antifeedant Nimbinim Limonim Synthesis of limonoid CDE fragments related to limonin and nimbinim info:eu-repo/semantics/article