TY - JOUR AU - Fernández Mateos, Alfonso AU - Encinas Madrazo, Soledad AU - Herrero Teijón, Pablo AU - Rabanedo Clemente, R. AU - Rubio González, María Rosa AU - Sanz González, Francisca AU - Fernández Mateos PY - 2013 SN - 0022-3263 UR - http://hdl.handle.net/10366/154245 AB - [EN]A practical, short, and diastereoselective synthesis of the azadiradione BCDE fragment from a readily available starting material is described. The key step was the titanocene(III)-promoted tandem cyclization of unsaturated epoxy nitrile. LA - eng KW - Anions KW - Cyclization KW - Hydrocarbons KW - Nitrogen compounds KW - Organic polymers TI - Synthesis of the BCDE Molecular Fragment of Azadiradione Mediated by Titanocene(III) DO - 10.1021/jo401646g T2 - The Journal of Organic Chemistry VL - 78 M2 - 9571 ER -