TY - JOUR AU - Fierro, J.L.G. AU - Martínez-Ripoll, M. AU - Merchán Moreno, María Dolores AU - Rodríguez, A. AU - Terreros, P. AU - Torrens, H. AU - Vivar-Cerrato, M.A. PY - 1997 SN - 0022-328X UR - http://hdl.handle.net/10366/158006 AB - [EN]The perfluorothiolate dinuclear compounds [Rh( ]A,-SC6E5XCOD)] 2 1 and [Rh( ]J~-SC6F5XCO)2] 2 2 react with PPh 3 to give monomeric and dimeric complexes, the particular product depending upon the PR3/Rh ratio and reaction conditions. Reaction of... LA - eng PB - Elsevier KW - Rhodium KW - Thiolate KW - X-ray diffractio KW - Hydroformylation TI - Rhodium(I) fluorothiolate complexes as hydroformylation catalyst precursors. Crystal structure of two polymorphs of trans-[Rh(SC6F5)(CO)(PPh3)2] DO - 10.1016/S0022-328X(97)00330-6 T2 - Journal of Organometallic Chemistry VL - 544 M2 - 243 ER -