TY - JOUR AU - Galán Fernández, Raquel AU - Clemente Tejeda, David AU - Río Nieto, Enrique del AU - Bermejo, Francisco A. PY - 2010 SN - 0040-4020 UR - http://hdl.handle.net/10366/170166 AB - [EN]A new route to racemic diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6- dicarboxylate (±)-1a by means of a palladium-catalyzed intramolecular allylic alkylation exercised on malonate-ester derivatives has been developed from R-(-)-carvone. The... LA - eng PB - Elsevier KW - Allylic alkylation KW - Monoterpenes KW - Pd catalysis KW - Stereoselective synthesis TI - Synthesis of diethyl 2-methyl-bicyclo[3.1.1]hept-2-ene-6,6-dicarboxylate by Pd-catalyzed intramolecular allylic alkylation. Stereoselective preparation of its optically homogeneous form from R-(−)-carvone DO - 10.1016/j.tet.2010.08.051 T2 - Tetrahedron VL - 66 M2 - 8247 ER -