TY - JOUR AU - Zanchet, Alexandre AU - Sanz-Sanz, Cristina AU - Ortega Álvarez, Pablo AU - García Jambrina, Pablo AU - Gómez Carrasco, Susana Raquel AU - González Sánchez, Lola PY - 2021 UR - http://hdl.handle.net/10366/146768 AB - [EN]Despite being a very strong oxidizing agent, most organic molecules are not oxidized in the presence of O2 at room temperature because O2 is a diradical whereas most organic molecules are closed-shell. Oxidation then requires a change in the spin... LA - eng KW - Charge transfer mechanism KW - Cofactor-independent enzymes KW - Oxidation KW - Oxygenases KW - Spin-forbidden transitions TI - DpgC-Catalyzed Peroxidation of 3,5-Dihydroxyphenylacetyl-CoA (DPA-CoA): Insights into the Spin-Forbidden Transition and Charge Transfer Mechanisms T2 - Chemistry-A European Journal VL - 27 M2 - 1700 ER -