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Título
Synthesis of the BCDE Molecular Fragment of Azadiradione Mediated by Titanocene(III)
Autor(es)
Palabras clave
Anions
Cyclization
Hydrocarbons
Nitrogen compounds
Organic polymers
Clasificación UNESCO
2306 Química Orgánica
Fecha de publicación
2013
Citación
Fernández Mateos, A., Herrero Teijón, P., Encinas Madrazo, S., Rabanedo Clemente, R., Rubio González, R. & Sanz González, F. (2013). Synthesis of the BCDE Molecular Fragment of Azadiradione Mediated by Titanocene(III). The Journal of Organic Chemistry, 78(19), 9571–9578. https://doi.org/10.1021/jo401646g
Resumen
[EN]A practical, short, and diastereoselective synthesis of the azadiradione BCDE fragment from a readily available starting material is described. The key step was the titanocene(III)-promoted tandem cyclization of unsaturated epoxy nitrile.
URI
ISSN
0022-3263
DOI
10.1021/jo401646g
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